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We present a rigorous quantum scattering study of the effects of hyperfine and Zeeman interactions on cold Li–H2 collisions in the presence of an external magnetic field using a recent ab initio potential energy surface. We find that the low-field-seeking states of H2 predominantly undergo elastic collisions: the ratio of elastic-to-inelastic cross sections exceeds 100 for collision energies below 100 mK. Furthermore, we demonstrate that most inelastic collisions conserve the space-fixed projection of the nuclear spin. We show that the anisotropic hyperfine interaction between the nuclear spin of H2 and the electron spin of Li can have a significant effect on inelastic scattering in the ultracold regime, as it mediates two processes: the electron spin relaxation in lithium and the nuclear spin–electron spin exchange. Given the predominance of elastic collisions and the propensity of inelastic collisions to retain H2 in its low-field-seeking states, our results open up the possibility of sympathetic cooling of molecular hydrogen by atomic lithium, paving the way for future exploration of ultracold collisions and high-precision spectroscopy of H2 molecules.more » « less
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Wcisło, Piotr; Wu, Hao; Reens, David; Aeppli, Alexander; Ye, Jun (, Measurement)
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Słowiński, Michał; Jóźwiak, Hubert; Gancewski, Maciej; Stankiewicz, Kamil; Stolarczyk, Nikodem; Tan, Yan; Wang, Jin; Liu, An-Wen; Hu, Shui-Ming; Kassi, Samir; et al (, Journal of Quantitative Spectroscopy and Radiative Transfer)
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Reens, David; Wu, Hao; Aeppli, Alexander; McAuliffe, Anna; Wcisło, Piotr; Langen, Tim; Ye, Jun (, Physical Review Research)null (Ed.)
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